we study the expansion of pluralia tantum, i.e., defective nouns which lack a singular form, like scissors. We base our work on an annotation framework specifically developed for the study of lexicalization of pluralia tantum, namely Lexicalization profiles. On a corresponding hand-annotated testset, we show that the OpenAI and DeepSeek models provide useful annotators for semantic, syntactic and sense categories, with accuracy ranging from 51% to 89%, averaged across all feature groups and languages. Next, we turn to a large-scale investigation of pluralia tantum. Using dictionaries, we extract candidate words for Italian, Russian and English and keep those for which the changing ratio of singular and plural form is evident in a corresponding reference corpus. We use an LLM to annotate each instance from the reference corpora according to the annotation framework. We show that the large amount of automatically annotated sentences for each feature can be used to perform in-depth linguistic analysis. Focusing on the correlation between an annotated feature and the grammatical form (singular vs. plural), patterns of morpho-semantic change are noted.